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991.
There are many examples of situations in which a gas-surface reaction rate is increased when the surface is simultaneously subjected to energetic particle bombardment. There are several possible mechanisms which could be involved in this radiation-enhanced gas-surface chemistry. In this study, the reaction rate of silicon, as determined from the etch yield, is measured during irradiation of the Si surface with 1 keV He+, Ne+, and Ar+ ions while the surface is simultaneously subjected to fluxes of XeF2 or Cl2 molecules. Etch yields as high as 25 Si atoms/ion are observed for XeF2 and Ar+ on Si. A discussion is presented of the extent to which these results clarify the mechanisms responsible for ion-enhanced gas-surface chemistry. 相似文献
992.
After presenting a procedure for finding exact solutions to the Gelfand-Levitan equation for inverse scattering, we present explicit solutions for 3- to 6-pole reflection coefficients. The method is applicable to an arbitrarily large number of poles. Here we give the first explicit treatment of 4, 5, and 6 poles. 相似文献
993.
994.
A method is developed to solve elliptic singular perturbation problems. Examples are presented in one and two dimensions for both linear and non-linear problems. In particular, examples are presented for fluid flow problems with boundary layers. In the one-dimensional case an approximating equation is developed using just three points. The method first presented is a fourth-order approximation but is extended to become a higher-order method. Results are included for the fourth-, sixth-, eighth- and tenth-order methods. The results are first compared with results found by Segal in an article about elliptic singular perturbation problems. The elliptic singular perturbation problems are compared with a method by Il'in and also with central and backward difference schemes from Segal's article. There was only one case where the results in Segal's paper were as accurate as the results presented in this paper. However, in this case the method used by Segal did not give accurate values for a second problem presented. The results are also compared with results given by Spalding and by Christie. The method of this paper was also tested on the solution of some non-linear diffusion equations with concentration-dependent diffusion coefficients. The results were superior to results presented by Lee and by Schultz. Finally, the method is extended to several two-dimensional problems. The method developed in this paper is accurate, easy to use and can be generalized to other problems. 相似文献
995.
Johan Vindevogel Roman Szücs Pat Sandra Leen C. Verhagen 《Journal of separation science》1991,14(9):584-586
The identification of beer bitter acids in a pre-isomerized hop extract by means of their UV-spectra is described. Preliminary data for the analysis of these compounds in beer samples are presented. 相似文献
996.
997.
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999.
Precise limiting ionic conductance data are reported for the first time for the alkali metal and tetraalkylammonium ions in D2O at 10°C as well as similar data for the halate and perhalate ions in D2O and H2O at 10 and 25°C. Precise transference numbers by the moving-boundary method are also reported for KBr in D2O at 10°C and, as a check on earlier work, for KCl in D2O at 25°C. In general, the structural properties of the ions, as reflected in the temperature coefficient of the limiting ionic conductances, are enhanced in D2O compared to H2O, although the differences are often small. 相似文献
1000.
Kay Niemax 《Journal of Quantitative Spectroscopy & Radiative Transfer》1977,17(6):747-750
The oscillator strengths of the forbidden lines of Rb (52S1/2-n2D5/2 and 52S1/2-n2D3/2, 4≤ n ≤9) have been measured in absorption. The dependence of the oscillator strength on the principal quantum number is qualitatively the same as calculated by Warner.(1) It was found that the values for the second quadrupole doublet are extremely small. 相似文献